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Cinigiano is a comune (municipality) in the Province of Grosseto in the Italian region Tuscany, located about 100 kilometres (62 mi) south of Florence and about 25 kilometres (16 mi) northeast of Grosseto. Cinigiano borders the following municipalities: Arcidosso, Campagnatico, Castel del Piano, Civitella Paganico, Montalcino.

Castiglioncello Bandini is a village in Tuscany, central Italy, administratively a frazione of the comune of Cinigiano, province of Grosseto. At the time of the 2001 census its population amounted to 93.Castiglioncello Bandini is about 50 km from Grosseto and 8 km from Cinigiano, and it is situated along the Provincial Road which links Monticello Amiata to Vallerona.

Borgo Santa Rita is a village in Tuscany, central Italy, administratively a frazione of the comune of Cinigiano, province of Grosseto. At the time of the 2001 census its population amounted to 34. Borgo Santa Rita is about 33 km from Grosseto and 10 km from Cinigiano. It is situated along the provincial road which links the Grosseto-Siena highway to the Mount Amiata.

Sant'Angelo Scalo is a village in Tuscany, central Italy, administratively a frazione of the comune of Montalcino, province of Siena. At the time of the 2001 census its population was 185. Sant'Angelo Scalo is about 60 km from Siena and 15 km from Montalcino.

Montenero d'Orcia is a village in Tuscany, central Italy, administratively a frazione of the comune of Castel del Piano, province of Grosseto, in the area of Mount Amiata. At the time of the 2001 census its population amounted to 253.Montenero is about 44 km from Grosseto and 14 km from Castel del Piano, and it is situated on a hill between the valley of Orcia and Ombrone rivers.

Monticello Amiata is a village in Tuscany, central Italy, administratively a frazione of the comune of Cinigiano, province of Grosseto. At the time of the 2001 census its population amounted to 425.

Stribugliano is a village in Tuscany, central Italy, administratively a frazione of the comune of Arcidosso, province of Grosseto, in the area of Mount Amiata. At the time of the 2001 census its population amounted to 253.Stribugliano is about 45 km from Grosseto and 18 km from Arcidosso, and it is situated on a peak of Monte Buceto above the valley of Melacce.

The Collemassari Winery (Cantina di Collemassari) is a contemporary-style winery located in the municipality of Cinigiano, in the province of Grosseto, Tuscany. The structure, designed by Edoardo Milesi and home to the winemaking company with the same name, is part of the Toscana Wine Architecture circuit of design wineries as one of Italy's "cathedrals of wine". It is located on a hill in the surroundings of the castle of Colle Massari, not far from the village of Poggi del Sasso. The winery is considered a valid example of sustainable architecture. In 2006, it won the 'Fassa Bortolo' International Prize for Sustainable Architecture, and in 2014, it was recognized as 'Winery of the Year' by the Gambero Rosso's Vini d'Italia guide. The winery's project was featured at the London Festival of Architecture in 2008, the 12th and 14th Venice Biennale in 2010 and 2012, and the 24th UIA World Congress of Architecture in Tokyo.

Monte Antico is a village in Tuscany, central Italy, administratively a frazione of the comune of Civitella Paganico, province of Grosseto, in the area of the Ombrone Valley. At the time of the 2001 census its population amounted to 33.

Monte Antico railway station is an Italian railway station on the Siena-Grosseto railway line in Monte Antico, Tuscany.

Poggi del Sasso is a village in Tuscany, central Italy, administratively a frazione of the comune of Cinigiano, province of Grosseto. At the time of the 2001 census its population amounted to 88.

Sasso d'Ombrone is a village in Tuscany, central Italy, administratively a frazione of the comune of Cinigiano, province of Grosseto. At the time of the 2001 census its population amounted to 300. Sasso d'Ombrone is about 33 km from Grosseto and 8 km from Cinigiano, and it is situated along the road which links Cinigiano to the Cipressino Provincial Road at Paganico, on a hill in the valley of Ombrone.